Beilstein J. Org. Chem.2014,10, 2157–2165, doi:10.3762/bjoc.10.223
developed is limited to benzylic, α-carbonyl, and α-cyanoalcohols; with other alcohols a slow partial C–F bond reduction in the 3,5-bis(trifluoromethyl)benzoate moiety occurs.
Keywords: C–Obondactivation; deoxygenation; photochemistry; photoredox catalysis; visible light; Introduction
The dwindling
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Graphical Abstract
Scheme 1:
Strategies for the visible light-catalysed deoxygenation of alcohols (reagents needed in (over-)sto...